3D mechanical metamaterials

Mechanical metamaterials derive their properties from architecture rather than composition, enabling mechanical behavior beyond bulk materials. Nanoscribe’s Two-Photon Polymerization enables high-resolution fabrication of complex 3D microstructures with submicron features, supporting rapid iteration and experimental validation of tailored mechanical performance.

Mechanical metamaterials defined by architecture

Engineering mechanical metamaterials through 3D architecture

Mechanical metamaterials are engineered materials whose properties arise from designed 3D architecture rather than composition alone. By structuring periodic or non-periodic structures, they exhibit unconventional behaviors such as negative Poisson’s ratio (auxetics), chiral responses, and enhanced energy absorption. At the microscale, fabricating mechanical metamaterials remains challenging due to the need for high precision, true 3D design freedom, and reliable process control.

High-precision 3D printing of mechanical metamaterials

Nanoscribe’s Two-Photon Polymerization (2PP) is a leading high-resolution 3D printing technology for fabricating mechanical metamaterials with complex freeform geometries. Quantum X systems, powered by Two-Photon Grayscale Lithography (2GL®), extend 2PP through voxel size tuning, realizing high-quality structures at significantly reduced fabrication times. This allows both fine features and large-scale architectures of engineered unit cells to be realized within a single workflow. The technology can also integrate different structural elements into one architecture, such as monolithic truss and woven designs, and introduce controlled defects to study energy dissipation effects.



 

The key benefits of high-resolution 3D printing

Quantum X systems combine precision, scalability, and design freedom, delivering clear advantages for mechanical metamaterial fabrication:

  • High throughput fabrication across scales: 2GL® accelerates printing from submicrometer features to mesoscale structures, supporting hierarchical designs. 

  • Aberration-free printing: Dip-in Laser Lithography (DiLL) ensures high shape fidelity and uniform feature sizes for predictable mechanical performance. 

  • Seamless 3D architectures: Automated cross-component calibrations ensure uniform pitches and minimize stitching artifacts, preserving mechanical behavior across large-area structures. 

  • Wide mechanical property range: Validated photoresins span Young’s moduli from the MPa to GPa range, allowing application-specific tuning from compliant to high-strength metamaterials. 

  • Compatible with pyrolytic post-processing: Nanoscribe’s photoresins convert into carbon nanostructures while preserving geometry for ultralight, high-strength and impact-resilient architectures. 

  • Streamlined lattice design: Included software accelerates the creation and modification of unit-cell architectures toward targeted mechanical properties.  

  • Direct printing on a wide range of substrates: Compatible with e.g. wafers, fibers, and MEMS, allowing in-situ fabrication for sensors, actuators and microdevices. 

Your questions answered: 3D printing of mechanical metamaterials

Which mechanical properties do Nanoscribe’s photoresins cover?

Nanoscribe photoresins cover a broad range of mechanical properties. The Young’s moduli of these materials range from the MPa to the GPa range. For example, IP-S and IP-Dip2 are designed for high stiffness, with Young’s moduli of approximately 2.1 GPa and 1.5 GPa, respectively. In contrast, IP-PDMS is a soft, flexible resin suited for elastic microstructures, offering exceptional stretchability of ≥240% elongation. 

For more detailed information on our photoresins and their properties, please contact us at sales@nanoscribe.com

Can pyrolysis improve the mechanical performance of printed metamaterials?

Yes. Pyrolysis can significantly enhance the mechanical performance of mechanical metamaterials printed with Two-Photon Polymerization (2PP). When polymer structures fabricated by 2PP using Nanoscribe’s photoresins undergo pyrolytic post-processing, they are converted into glassy (pyrolytic) carbon. 

This transformation results in mechanically robust nanoarchitectures with outstanding properties, including high specific energy absorption, strain-rate-independent compression behavior across a wide range of loading speeds, and strong impact resilience, even under supersonic loading conditions. 

Overall, pyrolysis increases stiffness, strength, and energy absorption compared to the original polymer structures, making it a powerful approach for high-performance metamaterials. 

Read more in this open-access publication: 
Quasi-Static to Supersonic Energy Absorption of Nanoarchitected Tubulanes and Schwarzites

 

Which design parameters control the behavior of mechanical metamaterials?

Mechanical metamaterial performance is mainly defined by 3D architecture. Parameters such as unit-cell geometry, lattice topology, strut diameter, pitch, hierarchy, orientation, and controlled defects can tune stiffness, auxetic behavior, damping, and energy absorption. Nanoscribe’s Two-Photon Polymerization, enhanced by Two-Photon Grayscale Lithography (2GL®) enable these parameters to be fabricated with high precision at the microscale, supporting rapid design iteration from compliant lattices to high-strength or impact-resilient architectures.

 

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Discover the potential of 3D-printed mechanical metamaterials

Get inspired by these scientific highlight publications, showcasing mechanical metamaterials created with Nanoscribe’s high-resolution 3D printing technology. For even more insights, explore over 2,500 peer-reviewed scientific publications in our premium resources section – simply log in or register for free.


Dynamic diagnosis of metamaterials through laser-induced vibrational signatures

Publication on Laptop

Y. Kai, S. Dhulipala, R. Sun, J. Lem, W. DeLima, T. Pezeril, C. M. Portela

Massachusetts Institute of Technology: Department of Mechanical Engineering, Institute for Soldier Nanotechnologies, Department of Chemistr

Nature 623, 514–521 (2023)

      

Experimental observation of roton-like dispersion relations in metamaterials

J. A. I. Martínez, M. F. Groß, Y. Chen, T. Frenzel , V. Laude, M. Kadic, M. Wegener

Université de Bourgogne Franche-Comté, Karlsruhe Institute of Technology (KIT)


Science Advances 7, eabm2189 (2021)

Supersonic impact resilience of nanoarchitected carbon

C. M. Portela , B. W. Edwards, D. Veysset , Y. Sun, K. A. Nelson , D. M. Kochmann , J. R. Greer
Massachusetts Institute of Technology, California Institute of Technology, ETH Zürich, The Kavli Nanoscience Institute at Caltech, Stanford University
Nature Materials 20, 1491–1497 (2021)

Three-dimensional mechanical metamaterials with a twist

Tobias Frenzel, Muamer Kadic, Martin Wegener

Institut für Angewandte Physik and DFG-Center for Functional Nanostructures (CFN), Universität Karlsruhe

Science 358,1072-1074 (2017)

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